Chromatography is a term that refers to a group of scientific procedures that are used to purify, separate, characterise, and identify the species in a mixture, whether coloured or colourless. The...
State the role of silica in the metallurgy of copper.
During roasting, copper pyrites are transformed to a combination of Cu2O and FeO. During the smelting process, acidic silica is introduced to separate the FeO from the mixture. FeSiO3 (slag) is...
Write chemical reactions taking place in the extraction of zinc from zinc blende.
The various steps involved in zinc extraction are : (1) Concentration of oreZinc blende is crushed first to eliminate impurities from the ore, and then froth flotation is used to concentrate the...
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
At 500 – 800 K3Fe2O3 +CO → 2Fe3O4 + CO2Fe2O3 +CO → 2FeO + CO2 At 850 KFe3O4 +CO → 3FeO + CO2 At 900 – 1500 KFeO +CO → Fe + CO2CO2 + C → 2CO Above 1570 KC+ O2 → CO2FeO +C → Fe + COCaCO3(s) → CaO(s) +...
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present ?
During the electrolytic refinement of copper, frequent components found in the anode mud include selenium, silver, tellurium, platinum, antimony, and gold.These metals are almost unaffected by the...
Out of C and CO, which is a better reducing agent at 673 K ?
CO is a more effective reducing agent at 673 K because the value of ∆G( C,CO ) is bigger than ∆G( CO,CO2 ), implying that CO is more easily reduced to CO2 than C to CO.
Explain Column chromatography.
Column chromatography: This is a great way to purify elements that are only present in trace levels. Column chromatography is commonly used to remove impurities that have chemical properties that...
Explain Zone refining.
Zone refining: The premise behind this approach is that contaminants are more soluble in molten metal than in solid metal. A rotating circular heater slowly glides over an impure metal rod or bar in...
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Copper (I) sulfite has a lower ∆fG (Gibbs free energy of formation) than hydrogen sulfite and carbon disulfite (CS2). As a result, neither C nor H2S will be able to convert Cu2S to Cu.Because...
What is the role of depressant in froth floatation process?
In froth flotation, the job of a depressant is to separate two sulphide ores by selectively preventing one ore from foaming. For example, to separate two sulphide ores, PbS and ZnS, NaCN is...
Copper can be extracted by hydrometallurgy but not zinc. Explain.
Copper's reduction potential is greater than that of zinc or iron. Iron and zinc can thus be employed to remove copper from a solution in hydrometallurgy. Fe(s) + Cu2+(aq) ⇒ Fe2+ (aq) + Cu(s)...
Question 12.19: An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.
Solution: The number of carbon, hydrogen, and oxygen atoms in an organic compound can thus be expressed as: Therefore, the empirical formula of the compound is C5H10O. Now, the empirical formula...
Question 12.20: Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Why?
Solution: The phenoxide ion has the following resonance structures: The resonance structures of the phenoxide ion show that less electronegative carbon atoms carry a negative charge in II, III, and...
Question 12.18: Give a plausible explanation for: (iii) During the preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, the water or the ester should be removed as soon as it is formed.
Solution: In the presence of an acid, an ester along with water is generated reversibly from a carboxylic acid and an alcohol. Because the reaction is reversible, if either water or ester is not...
Question 12.18: Give a plausible explanation for: (ii) There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
Solution: Only one of the two −NH2 groups, which is connected directly to the carbonyl-carbon atom, undergoes resonance in semicarbazide. As a result, the electron density on the −NH2 group in the...
Question 12.18: Give a plausible explanation for: (i) Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Solution: (i) According to the equation below, cyclohexanones produce cyanohydrins. There will be no steric hindrance in this situation, allowing the nucleophile CN– to attack with ease. However,...
Question 12.25: Complete each synthesis by giving missing starting material, reagent or products
Solutions:
Question 12.24: Complete each synthesis by giving missing starting material, reagent or products
Solutions:
Question 12.23: Complete each synthesis by giving missing starting material, reagent or products
Solutions:
Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl ( primary, secondary, tertiary ), vinyl, or aryl halides :
(i) (CH3)2CHCH(Cl)CH3 (ii) CH3CH2CH(CH3)CH(C2H5)Cl Solution: (i) 2 − Chloro − 3 – methylbutane (Secondary alkyl halide) (ii) 3 − Chloro − 4 – methyhexane (Secondary alkyl...
Question 12.22: Complete each synthesis by giving missing starting material, reagent or products.
Solutions:
Question 12.21: Complete each synthesis by giving missing starting material, reagent or products.
Solutions:
Question 12.20: Complete the synthesis by giving missing starting material, reagent or products.
Solution:
Question 12.19: Describe decarboxylation.
Decarboxylation is the process by which carboxylic acids lose carbon dioxide and create hydrocarbons when their sodium salts are heated with soda-lime. Decarboxylation occurs when alkali metal salts...
Question 12.18: Describe Cross aldol condensation.
Cross-aldol condensation occurs when two different aldehydes, two different ketones, or an aldehyde and a ketone react together. If both reactants contain α-hydrogens, four compounds are produced as...
Question 12.17: Describe Cannizzaro reaction.
The self-disproportionation (oxidation-reduction) reaction of aldehydes with no alpha hydrogens, when treated with concentrated alkalis, is known as the Cannizzaro reaction. In this reaction, one...
Question 12.16: Describe Acetylation.
Acetylation is the process of adding an acetyl function group to a chemical molecule. When this process is carried out, bases such as pyridine, dimethylaniline, and others are present. In this...
Question 12.15.5: How will you bring about the following conversions in not more than two steps? (ix) Benzoic acid to m- Nitrobenzyl alcohol
Question 12.15.4: How will you bring about the following conversions in not more than two steps? (vii) Benzaldehyde to 3-Phenylpropan-1-ol (viii) Benazaldehyde to α-Hydroxyphenylacetic acid
Question 12.15.3: How will you bring about the following conversions in not more than two steps? (v) Benzaldehyde to Benzophenone (vi) Bromobenzene to 1-Phenylethanol
Question 12.15.2: How will you bring about the following conversions in not more than two steps? (iii) Ethanol to 3-Hydroxybutanal (iv) Benzene to m-Nitroacetophenone
Question 12.15.1: How will you bring about the following conversions in not more than two steps? (i) Propanone to Propene (ii) Benzoic acid to Benzaldehyde
Question 12.14: How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom. (v) p-Nitrobenzaldehyde
Question 12.14: How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom. (iii) p-Nitrobenzoic acid (iv) Phenylacetic acid
Question 12.14: How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom. (i) Methyl benzoate (ii) m-Nitrobenzoic acid
Solution:
Question 12.13: Give simple chemical tests to distinguish between the following pairs of compounds. (i) Propanal and Propanone (ii) Acetophenone and Benzophenone (iii) Phenol and Benzoic acid (iv) Benzoic acid and Ethyl benzoate (v) Pentan-2-one and Pentan-3-one (vi) Benzaldehyde and Acetophenone (vii) Ethanal and Propanal
Solution: (i) Propanal and propanone can be distinguished by the following tests. (a) Tollen’s test Because propanal is an aldehyde, it reduces Tollen's reagent. However, because propanone is a...
Question 12.12: Arrange the following compounds in increasing order of their property as indicated: (i) Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN) (ii) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH (acid strength) (iii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)
Solution: (i) The attacking species when HCN reacts with a compound, is a nucleophile, CN–. The reactivity of HCN decreases when the negative charge on the compound increases. The +I effect and...
Q4. (i) What is meant by the term ‘coordination number’?
(ii) What is the coordination number of atoms:
(a) in a cubic close-packed structure?
(b) in a body-centred cubic structure?
(i) Coordination number is the number of nearest neighbours around a particle.(ii) (a) coordination number of close-packed structure is 12 (b) coordination number of body centred cubic...
Classify each of the following solids as ionic, metallic, molecular, network (covalent) or amorphous.
(a) Tetra phosphorus decaoxide (P4O10)
(b) Ammonium phosphate (NH4)3PO4
(c) SiC
(d) I2
(e) P4
(f) Plastic
(g) Graphite
(h) Brass
(i) Rb
(j) LiBr
(k) Si
Metallic : ( h ) Brass, ( i ) Rb Molecular : (a) Tetra phosphorus decaoxide (P4O10), (d) I2, (e) P4. Ionic : ( b ) Ammonium phosphate (NH4)3PO4, ( j ) LiBr Amorphous : ( f )...
What makes a glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?
The arrangement of the constituent particles makes a glass different from a solid such as quartz. The constituent particles in glass are of a short-range order, but the constituent particles of...
Question 12.11: An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.
Solution: According to the question, A is an organic compound having molecular formula C8H16O2. This gives a carboxylic acid (B) and an alcohol (C) on hydrolysis with dilute sulphuric acid. Thus,...
Question 12.10: An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1,2-benzenedicarboxylic acid. Identify the compound.
Solution: According to the question, the compound has molecular formula C9H10O and forms 2, 4-DNP derivative while also reducing Tollen’s reagent. Therefore, the given compound must be an aldehyde....
An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. Write the structures and IUPAC names of compounds A, B, and C.
Compound ‘C,' with the molecular formula C6H7N, is created by heating compound ‘B' with Br2 and KOH, according to the formula. This is a decomposition of Hoffmann bromamide. As a result, compound B...
Question 12.9: Write structural formulae and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile
Solution: (i) One molecule of propanal acts as a nucleophile and the other molecule acts as an electrophile. (ii) One molecule of butanal acts as a nucleophile and the other as an...
Question 12.8: How will you convert ethanal into Butane-1, 3-diol?
Solution: Ethanal on reaction with dilute alkali produces 3-hydroxybutanal and then on further reduction with NaBH4 gives butane-1, 3-diol.
Question 12.7: Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction. (i) Methanal (ii) 2-Methylpentanal (iii) Benzaldehyde (iv) Benzophenone (v) Cyclohexanone (vi) 1-Phenylpropanone (vii) Phenylacetaldehyde (viii) Butan-1-ol (ix) 2, 2-Dimethylbutanal
Solution: The compounds (ii) 2−methylpentanal, (v) cyclohexanone, (vi) 1-phenylpropanone, and (vii) phenylacetaldehyde contain one or more α-hydrogen atoms. Therefore, these undergo aldol...
Define the term ‘amorphous’. Give a few examples of amorphous solids.
Amorphous solids are solids having no regular arrangements of their constituent particles like ions, atoms or molecules. They possess short-range order i.e., a regular and periodically repeating...
Question 12.6: Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents: (i) PhMgBr and then H3O+ (ii)Tollens’ reagent (iii) Semicarbazide and weak acid (iv)Excess ethanol and acid (v) Zinc amalgam and dilute hydrochloric acid
Solution:
Question 12.5: Draw structures of the following derivatives.
(i) The 2,4-dinitrophenylhydrazone of benzaldehyde (ii) Cyclopropanone oxime (iii) Acetaldehydedimethylacetal (iv) The semicarbazone of cyclobutanone (v) The ethylene ketal of hexan-3-one (vi) The...
Question 12.4: Write the IUPAC names of the following ketones and aldehydes. Wherever possible, give also common names.
(i) CH3CO(CH2)4CH3 (ii) CH3CH2CHBrCH2CH(CH3)CHO (iii) CH3(CH2)5CHO (iv)Ph-CH=CH-CHO (v) (vi) PhCOPh Solution: (i) CH3CO(CH2)4CH3 IUPAC name: Heptan-2-one Common name: Methyl pentyl ketone (ii)...
Question 12.3: Draw the structures of the following compounds.
(i) 3-Methylbutanal (ii) p-Nitropropiophenone (iii) p-Methylbenzaldehyde (iv)4-Methylpent-3-en-2-one (v) 4-Chloropentan-2-one (vi) 3-Bromo-4-phenylpentanoic acid (vii)...
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
A biodegradable polymer is a polymer that microorganisms can degrade. An example of aliphatic biodegradable polyester is a poly-β-hydroxybutyrate-CO-β-hydroxy valerate (PHBV).
How is dacron obtained from ethylene glycol and terephthalic acid?
The condensation polymerization of terephthalic acid and ethylene glycol produces dacron. The reaction demonstrating the same is as follows:
Identify the monomer in the following polymeric structures:
(i) (ii) Solution: (i) The monomers of the given polymeric structure are hexamethylene diamine [H2N(CH2)6NH2] and decanoic acid [HOOC – (CH2)8 – COOH]. (ii) The following are the monomers that make...
Write the names and structures of the monomers of the following polymers: (i) Buna-S (ii) Buna-N (iii) Neoprene (iv) Dacron
The names and structures of the given polymers are as follows:
What are the monomeric repeating units of Nylon-6 and Nylon-6,6?
The [NH - (CH2)5 –CO] monomeric repeating unit of Nylon-6 is obtained from Caprolactam. The [NH – (CH2)6 - NH CO – (CH2)4 – CO] monomeric repeating unit of nylon-6, 6 is made up of diamine...
List the uses of neon and argon gases.
Application of neon gas:(a) Neon is filled in discharge tubes for advertising or decoration as it glows.(b) It is used for making beacon lights.(c) It is used alongside helium to protect electrical...
Why do noble gases have comparatively large atomic sizes?
Noble gases have atomic radius that corresponds to the Van der Waal’s radius. Whereas, other elements consist of a covalent radius. The Van der Waal’s radius is bigger than covalent radius. For this...
Give the formula and describe the structure of a noble gas species which is isostructural with:
( a ) ICl4–
( b ) IBr2–
( c ) BrO3–
(a) XeF4 is isoelectronic to ICl4–. And it has a square planar geometry. Its structure can be drawn as follows: (b) XeF2 is isoelectronic with IBr2–. It has a linear structure. Its structure can be...
Which one of the following does not exist?
(i) XeOF4 (ii) NeF2 (iii) XeF2 (iv) XeF6
The one that does not exist is NeF2 due to the small sizes of both neon and fluorine which causes high electronic repulsions among the atoms which disrupts the overall stability of the compound.
Arrange the following in the order of property indicated for each set:
(i) F2, Cl2, Br2, I2 – increasing bond dissociation enthalpy.
(ii) HF, HCl, HBr, HI – increasing acid strength.
(iii) NH3, PH3, AsH3, SbH3, BiH3 – increasing base strength.
(1) Bond dissociation energy normally decreases while moving down a group because of the increase in the atomic size. However, F2 has a lower bond dissociation energy than Cl2 and Br2 because of the...
How are XeO3 and XeOF4 prepared?
XeO3 can be obtained using the following two methods:1) \[6Xe{{F}_{4}}~+\text{ }12{{H}_{2}}O\to 4Xe\text{ }+\text{ }2Xe{{O}_{3}}~+\text{ }24HF\text{ }+\text{ }3{{O}_{2}}\]2)...
With what neutral molecule is ClO– isoelectronic? Is that molecule a Lewis base?
ClO– is isoelectronic with ClF.Total number of electrons in ClO– = 17 + 8 + 1 =26Total number of electrons in ClF = 17 + 9 = 26As ClF accepts electrons from fluorine to form ClF3 ,...
How are xenon fluorides XeF2, XeF4 and XeF6 obtained?
XeF2, XeF4 and XeF6 are obtained through direct chemical reactions occurring between Xe and F2. The product of the chemical reaction depends upon the conditions of the...
Write balanced equations for the following:
(i) NaCl is heated with sulphuric acid in the presence of MnO2.
(ii) Chlorine gas is passed into a solution of NaI in water.
The balanced chemical equation for the given reactions are as follows: (i) \[4NaCl\text{ }+\text{ }Mn{{O}_{2~}}+\text{ }4{{H}_{2}}S{{O}_{4}}\to MnC{{l}_{2}}~+\text{ }4NaHS{{O}_{4}}~+\text{...
What are the oxidation states of phosphorus in the following:
( a ) H3PO3( b ) PCl3( c ) Ca3P2( d ) Na3PO4( e ) POF3? Let the oxidation state of phosphorous in each case be y.(a) H3PO33 + y + 3( -2) = 0y -3 = 0y =3 (b) PCl3y + 3( -1) = 0y = 3 (c) Ca3P23( 2 ) +...
What inspired N. Bartlett for carrying out reaction between Xe and PtF6?
A chemist named N.Barlett observed that PtF6 and O2 react with each other to yield a compound O2+[ PtF6]–.As the first ionization enthalpy of Xe (1170 kJ/mol) is very close to that of the...
How can you prepare Cl2 from HCl and HCl from Cl2? Write reactions only.
(1) Preparation of HCl from Cl2 :\[C{{l}_{2}}~+\text{ }{{H}_{2}}O\to HCl\text{ }+\text{ }HOCl\] (2) Preparation of Cl2 from HCl (by Deacon’s process):\[4HCl+{{O}_{2}}~\to 2C{{l}_{2}}~+\text{...
Write the reactions of F2 and Cl2 with water.
(1) Reaction of chlorine with water: \[C{{l}_{2}}~+\text{ }{{H}_{2}}O~\to HCL\text{ }+\text{ }HOCL\] (2) Reaction of fluorine with water:\[2{{F}_{2}}~+\text{ }2{{H}_{2}}O\to 4{{H}^{+}}~+\text{...
Why are halogens coloured?
Halogens appear to be coloured because they accept radiations from the visible spectrum. This causes excitation of the valence electrons to a higher energy level. The amount of energy required for...
Write two uses of ClO2.
Any two applications of ClO2 are as follows: It is used in the purification of water.It is used for bleaching.
Explain why in spite of nearly the same electronegativity, nitrogen forms hydrogen bonding while chlorine does not.
Because of oxygen atom’s smaller size and higher electron density per unit volume, oxygen forms hydrogen bonds whereas chlorine does not form hydrogen bonds despite having similar electronegative...
Explain why fluorine forms only one oxoacid, HOF.
Due to its high electronegativity and small size, fluorine forms only one oxoacid i.e HOF.
Why are halogens strong oxidising agents?
Halogens have a general electronic configuration of np5, where n =2 to 6. Thus, halogens require only one more electron to complete their octet and to attain the nearest noble gas configuration....
How is SO2 an air pollutant?
Sulphur dioxide harms the environment in many ways: The sulphuric acid formed when combined with water vapour present in the atmosphere causes damages to the plants, soil, buildings (those made of...
Describe the manufacture of H2SO4 by contact process.
The steps which are required in the production of Sulphuric Acid by the contact process are mentioned as follows: Step 1: Sulphide ores or Sulphur are burnt in air to form sulphur dioxide or...
Which aerosols deplete ozone?
The aerosols which are responsible for the depletion of ozone are Freons or chlorofluorocarbons (CFCs). The molecules of CFCs break down in the presence of ultraviolet radiations and form chlorine...
Knowing the electron gain enthalpy values for O → O-1 and O → O-2 as −141 and 702kJmol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O−?
(Hint: Consider lattice energy factor in the formation of compounds).
More the value of lattice energy of a given compound, more will be its stability. The stability of an ionic compound depends on the value of its lattice energy. Lattice energy is directly...
Why is dioxygen a gas but sulphur a solid?
Oxygen atom is smaller in size in comparison to sulphur atom. Since its size is small, it can form pπ−pπ bonds and form O2(O=O) molecule. Along with that, the intermolecular forces of attraction in...
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
The group 16 elements are collectively known as chalcogens.(i) The elements of group 16 have six valence electrons each. The general electronic configuration of these elements is ns2np4, where...
Can PCl5 act as an oxidising as well as a reducing agent? Justify.
PCl5 can only act as an oxidizing agent and not as a reducing agent. The highest oxidation state that P can undergo is +5. In phosphorous pentachloride, PCl5, phosphorus is in its highest...
Why does nitrogen show catenation properties less than phosphorus?
Catenation is much more common in phosphorous compounds than in nitrogencompounds because of the relative weakness of the N−N single bond as comparedto the P−P single bond. The self-linking tendency...
How is ammonia manufactured industrially?
Ammonia is prepared in the industries on a large-scale with the help of the Haber’s process.\[{{N}_{2}}\left( g \right)\text{ }+\text{ }3{{H}_{2}}\left( g \right)\rightleftharpoons 2N{{H}_{3}}\left(...
Discuss the main purpose of the vulcanization of rubber.
Natural rubber is beneficial but also has drawbacks. The disadvantages of natural rubber are as follows: Natural rubber is sticky and soft at room temperature. At higher temperatures, above 335 K,...
How does the presence of double bonds in rubber molecules influence their structure and reactivity?
Natural rubber is a cis-polyisoprene with double bonds between the two isoprene units, C2 and C3. Intermolecular interactions between the multiple isoprene units are relatively weak due to their...
Write the name and structure of one of the common initiators used in free radical addition polymerization.
One of the most popular initiator names and structures used in free radical polymerization is benzoyl peroxide.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
Monomers used: (1) Vinyl chloride (CH2=CHClCH22=CHCl)(2) Tetrafluoroethylene (CF2= CF2 CF2=CF2)(3) Phenol (C6H5OHC6H5OH) and Formaldehyde (HCHO)
Define thermoplastics and thermosetting polymers with two examples of each.
The term "thermosetting polymers" refers to cross-linked or heavily branched polymers that harden during the molding process. They cannot be softened any further by heating. For example, Bakelite is...
Write the free radical mechanism for the polymerisation of ethene.
Free radical mechanism of ethene consists of three steps which are as follows:- (i) Chain initiation step: (ii) Chain propagation step: (iii) Chain termination step:...
Explain the term copolymerization and give two examples.
The mechanism by which polymers are produced from two or more monomeric units is known as co-polymerization. There are several units of each monomer in a copolymer. Following are the two examples of...
How can you differentiate between addition and condensation polymerization?
Addition Polymerization Condensation Polymerization 1. Monomers must have either a double bond or triple bond 1. Monomers must have two similar or different functional groups 2. No by-products are...
Determine the groups where the polymers are graded according to molecular forces?
Based on the number of intermolecular forces present in polymers, polymers are divided into the following groups: (a) Fibres (b) Elastomers (c) Thermosetting polymers (d) Thermoplastic...
Is ( NH-CHR-CO )n, a homopolymer or copolymer?
(−NH—CHR—CO−)n is a homopolymer because it is derived from a single monomeric unit, (-NH-CHR-CO-)
Define the term polymerization.
Polymerization is the process of producing macromolecules with a large molecular mass falling in the range 10-3 -10-7u that are made up of repetitive structural units called monomers. A polymer is...
How do you explain the functionality of a monomer?
Functionality is the number of binding sites present in a monomer.The monomers ethene and propene, for example, each have a functionality of one.Each of the monomers 1,3-butadiene and adipic acid...
What are natural and synthetic polymers? Give two examples of each type.
Natural polymers are polymers that occur naturally. Polymers derived from animals and plants are known as natural polymers. Protein, starch, cellulose, and other natural polymers are examples....
Write the important structural and functional differences between DNA and RNA.
The following is the distinction based on their functions: DNA is the basis of heredity while RNA is not involved in heredity. The following are the differences between them based on their...
Differentiate between globular and fibrous proteins.
Globular proteinFibrous protein1. Globular protein consists of a polypeptide chain that is folded around itself which gives rise to a spherical structure.1. Fibrous protein is a fiber-like structure...
Explain the terms polymer and monomer.
Polymers are macromolecules with a large molecular mass that are made up of repeated monomer-derived structural units. Polymers have an enormous molecular mass of 10-3-10-7u. Covalent bonds join a...
What is the difference between a nucleoside and a nucleotide?
A nucleotide is formed when the three basic components of nucleic acids are combined (i.e., base, a pentose sugar, and phosphoric acid). As a result, a nucleotide is made up of three components:...
What are nucleic acids? Mention their two important functions.
It is a molecule that is found in the nucleus of all live cells and is one of the constituents of chromosomes. There are two types of nucleic acid: ribonucleic acid (RNA) and deoxyribonucleic acid...
Why are vitamin A and vitamin C essential to us? Give their important sources.
Vitamin A and Vitamin C are the two vitamins that are necessary for us since their deficiency can cause dangerous diseases, such as xerophthalmia (hardening of the cornea) and night blindness....
How are vitamins classified? Name the vitamin responsible for the coagulation of blood.
Vitamins are divided into two categories based on their solubility in water or fat. (a) Water-Soluble Vitamins: This category includes vitamins that are water-soluble. B vitamins (B1,B2, B12 etc.)...
What is the effect of denaturation on the structure of proteins?
Denaturation results in the uncoiling of protein helixes and the unfolding of globules. The core structure of the protein does not change, but the secondary and tertiary structures are destroyed....
What are enzymes?
Enzymes are proteins that catalyze biological reactions. They are quite specific in nature, and they catalyze specific reactions for a certain substrate. The enzymes are named after a specific...
How do you explain the amphoteric behavior of amino acids?
The carboxyl group of an amino acid can lose a proton and the amino group can take up a proton in the presence of water or aqueous solution, resulting in a dipolar ion known as a zwitter ion. As a...
What type of bonding helps in stabilizing the α-helix structure of proteins?
The H-bonds formed between the -NH group of each amino acid residue and the -OH group of the adjacent turns of the α-helix aid in helix stabilization.
Define the following as related to proteins (i) Primary structure (ii) Peptide linkage (iii) Denaturation.
(i) Primary structure When we discuss the primary structure of a protein, we refer to the exact sequence in which the amino acids are present. For example, the sequence of amino acid linkages in a...
What are essential and non-essential amino acids? Give two examples of each type.
Essential amino acids are those that are required by the human body but cannot be synthesized by the body. They must be obtained from an outside source, such as food. Consider the amino acids...
Enumerate the reactions of D-glucose which cannot be explained by its open-chain structure.
(i) The glucose pentaacetate does not react with hydroxylamine. This demonstrates that glucose does not include a free -CHO group. (ii) Aldehydes produce hydrogen sulfite as a byproduct by giving...
What happens when D-glucose is treated with the following reagents? (i)HI (ii) Bromine water (iii)HNO3
(i) When D-glucose is heated with HI for a long time, n-hexane is produced. (ii) D-glucose is converted to D-gluconic acid when it is treated with Bromine water. (iii) After being treated with HNO3,...
What is the basic structural difference between starch and cellulose?
Starch consists of amylopectin and amylose subunits. Amylose has a long linear chain of alpha – D (+)glucose units linked together by a C1-C4 glycosidic bond (alpha -link). Figure :- Amylose While...
What are the hydrolysis products of (i) sucrose and (ii) lactose?
(i) One molecule of α-D glucose and one molecule of β-D fructose are produced when sucrose is hydrolyzed. (b) When lactose is hydrolyzed, it produces beta-D-galactose and beta-D-glucose
What is glycogen? How is it different from starch?
Glycogen, commonly known as animal starch, is a type of carbohydrate found solely in animals. It is made up of polysaccharides. Glycogen and starch are the two primary sources of glucose in humans....
What do you understand by the term glycosidic linkage?
The glycosidic bond is formed when water is lost between two monosaccharide units bypassing via an oxygen atom. A glycosidic linkage, for example, connects two monosaccharide units, α-glucose,...
Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose
2-deoxyribose, galactose, ribose, and fructose are monosaccharides. Lactose and maltose are two disaccharides.
Write two main functions of carbohydrates in plants.
The two main functions of carbohydrates in plants are as follows:- (a) Starch and other polysaccharides act as storage molecules. (b) Cellulose is a polysaccharide that is present as a cell wall...
What are reducing sugars?
Reducing sugars are those carbohydrates that reduce Fehling's solution and Tollen's reagent. These act as reducing agents due to the presence of free aldehyde and ketone groups. All monosaccharides...
What are monosaccharides?
Monosaccharides are simple sugars that contain one sugar unit and cannot be broken down further into simple sugars. The number of carbon atoms and the functional group present in a monosaccharide...
Label the hydrophilic and hydrophobic parts in the following compounds.
Solution:
If the water contains dissolved calcium hydrogencarbonate, out of soaps and synthetic detergents which one will you use for cleaning clothes?
Clothes are frequently washed with synthetic detergents instead of soaps. When soap ions are dissolved in water containing calcium ions, they create insoluble compounds that are useless. Synthetic...
Explain the cleansing action of soaps.
Soap molecules form micelles around an oil droplet (drit) in such a way that the hydrophobic ends of the stearate ions are attached to the oil droplet and the hydrophilic ends of the stearate ions...
Can you use soaps and synthetic detergents to check the hardness of water?
Soaps precipitate in hard water, but not in soft water, and can thus be used to determine the hardness of the water. Synthetic detergents, on the other hand, do not precipitate in both hard and soft...
Why do soaps not work in hard water?
Soaps contain sodium or potassium salts containing long-chain fatty acids. Magnesium and calcium are present in hard water. Insoluble calcium or magnesium salts of fatty acids occur when ions...
What are biodegradable and non-biodegradable detergents? Give one example of each.
Detergents that are degraded by microorganisms are known as biodegradable detergents. They have hydrocarbon chains that are straight. For instance, sodium lauryl sulfate. Non-biodegradable...
Explain the following terms with suitable examples: (i) cationic detergents, (ii) anionic detergents, and (iii) non-ionic detergents.
(i) Cationic detergents: Compound detergents in which the cationic component has a longer hydrocarbon chain and a positive charge on the N atom are called cationic detergents. Quaternary ammonium...
How are synthetic detergents better than soaps?
In both soft and hard water, synthetic detergents are utilized, while soaps are used in soft water. Soaps are ineffective in hard water. As a result, synthetic detergents are preferable to soaps.
What problem arises in using alitame as an artificial sweetener?
Alitame is a highly effective sweetener. It is tough to control the sweetness of food when using alitame as an artificial sweetener.
Name the sweetening agent used in the preparation of sweets for a diabetic patient.
Sweetening chemicals such as saccharin, aspartame, and alitame are used to prepare diabetic sweets.
What are artificial sweetening agents ? Give two examples.
Artificial sweeteners are chemicals that are used to sweeten meals. Artificial sweeteners do not add calories to our diets and are not harmful to our health. Sucralose, aspartame, alitame, and...
Why is the use of aspartame limited to cold foods and drinks?
Because aspartame is unstable at high temperatures, it can only be used in cold foods and beverages.
What are food preservatives?
Food preservatives are chemicals that limit microbial growth in food. They minimize spoiling. Sugar, table salt, vegetable oil, propanoic acid salts, and sodium benzoate are examples of food...
What is the tincture of iodine? What is it used for?
Iodine tincture is a mixture of alcohol and water that contains 2-3 % iodine and is used to treat wounds.
How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions involved.
When an aqueous solution of ammonium chloride is treated with sodium nitrite, nitrogen gas is released along with water and an aqueous solution of sodium chloride. The reaction can be written as...
Why does NH3 form hydrogen bond but PH3 does not?
When nitrogen is compared to phosphorus, nitrogen is comparatively of higher electronegativity. This causes a greater attraction of electrons towards nitrogen in NH3 than towards phosphorus atom...
What are the main constituents of Dettol?
Principle constituents of Dettol are chloroxylenol and alpha−terpineol.
Name a substance which can be used as an antiseptic as well as a disinfectant.
Phenol is a chemical that can be used as a disinfectant as well as an antiseptic. As an antiseptic, a 0.2% phenol solution is used, and 1% of the solution is used as a disinfectant.
Why are cimetidine and ranitidine better antacids than sodium hydrogen carbonate or magnesium or aluminium hydroxide?
Magnesium hydroxide, sodium hydrogen carbonate, and aluminum hydroxide are antacids that neutralize excess hydrochloric acid in the stomach. The reason for releasing extra acid, on the other hand,...
How do antiseptics differ from disinfectants? Give one example of each.
Disinfectants and antiseptics are extremely effective against microorganisms. Antiseptics are used on living tissues while disinfectants are used for non-living surfaces. Cuttings, wounds, diseased...
What is meant by the term ‘broad spectrum antibiotics’? Explain.
Broad-spectrum antibiotics are medicines that work against a wide range of gram-negative and gram-positive bacteria. Chloramphenicol, for example. Acute fever, typhoid, meningitis, dysentery, TB,...
A low level of noradrenaline is the cause of depression. What type of drugs are needed to cure this problem? Name two drugs.
Antidepressant medications are used to alleviate the symptoms of depression. These medications contain enzymes that catalyze the breakdown of noradrenaline, a neurotransmitter. As a result, the...
While antacids and antiallergic drugs interfere with the function of histamines, why do these not interfere with the function of each other?
Certain medications have a specific effect on specific receptors. Antacids and antiallergic medicines function on different receptors, thus they don't interfere. That's why antacids and antiallergic...
Which forces are involved in holding the drugs to the active site of enzymes?
The forces responsible for holding the drugs to the active site of enzymes are:(a) Hydrogen bonding (b) Ionic bonding (c) van der Waals force (d) Dipole-dipole interaction
Define the term chemotherapy.
Chemotherapy is the application of chemicals for therapeutic purposes. Chemical agents are used for illness prevention, diagnosis, and therapy.
Why should medicines not be taken without consulting doctors?
Because medicines can bind to several receptor sites, they should not be taken without visiting a doctor. As a result, some receptor sites may be harmed. When medicines are taken in higher doses,...
Name the macromolecules that are chosen as drug targets.
The macromolecules used as drug targets include carbohydrates, lipids, proteins, and nucleic acids.
Explain the terms target molecules or drug targets as used in medicinal chemistry.
The target molecules are the major molecules involved in a number of metabolic pathways that might lead to disease. Proteins, nucleic acids, carbohydrates, and lipids are the drug targets. Chemical...
Why do we need to classify drugs in different ways?
The following are the reasons for the classification of drugs: (i) The pharmacological effect is based on the following: This definition is beneficial to physicians. It offers a wide range of...
Comment on the statement that “colloid is not a substance but a state of substance”.
In a benzene medium, common salt which is a typical crystalloid in an aqueous medium acts as a colloid. As a result, we can claim that colloidal substances do not belong to a distinct class of...
Explain the terms with suitable examples:
(i) Alcosol
(ii) Aerosol
(iii) Hydrosol
Solution : (ii) Alcosol: An alcosol is a colloidal solution in which the dispersed phase is a solid substance and the dispersion medium is alcohol. For example, a colloidal sol of cellulose nitrate...
What are micelles? Give an example of a micellar system.
Micelle is formed when soaps and detergents are dissolved in water. Micelle consists of hydrophobic and hydrophilic parts. When present in water, they form spherical formations with their...
Give four uses of emulsions.
Emulsions are used for a variety of purposes. Four uses of emulsions have been listed below: (i) The cleansing action of soap is determined by the formation of emulsions. (ii) The emulsification...
Explain the following terms:
(ii) Coagulation
(iii) Dialysis
(iv)Tyndall effect
Solution: (i) Electrophoresis: It is the process of causing colloidal particles to move randomly in response to an applied electric field. The anode attracts negatively charged...
What is shape-selective catalysis?
Shape-selective catalysis is a catalytic reaction that depends on the product molecules, the size of the reactants, and the pore structure and size of the catalyst. For example, a catalytic process...
Describe some features of catalysis by zeolites.
Some features of catalysis by zeolites are listed below:- (i) Zeolites are alumino-silicates that are naturally microporous. (ii) Because of their honeycomb-like structure, zeolites are...
What do you mean by activity and selectivity of catalysts?
a) Activity: The ability of a catalyst to enhance the rate of a reaction is referred to as its activity. The main factor, chemisorption, determines a catalyst's activity. The process should be...
Give four examples of heterogeneous catalysis.
(i) Sulphur trioxide is generated when sulphur dioxide is oxidised. Pt acts as a catalyst in this process. 2SO2(g) → Pt(s) + 2SO3(g) (ii) Ammonia is formed when dinitrogen and dihydrogen are...
The action of soap is due to emulsification and micelle formation. Justify.
The cleansing activity of soap is determined by emulsification and micelle production. The basic combination of soap contains sodium and potassium salts of long-chain fatty acids (R-COO-Na+). The...
How do emulsifiers stabilize emulsion? Name two emulsifiers.
Emulsifiers stabilise an emulsion by lowering the interfacial tension between the two liquids that make up the emulsion. Emulsifiers are long-chain compounds having polar groups. For instance,...
How are colloids classified on the basis of – (i) physical states of components (ii) nature of dispersed phase and (iii) interaction between the dispersed phase and dispersion medium?
Colloids are classified in a variety of ways : (I) The dispersed phase and dispersion medium, or the physical state of the components, are referred to as components. As a result, depending on...
Define enzymes. Briefly describe the mechanism of enzyme catalysis.
Enzymes are large protein molecules with a high molecular mass. When they are dissolved in water, colloidal solutions are created. Living plants and animals manufacture these complex nitrogenous...
Write the differences between multimolecular and macromolecular colloids. Give one example of each. How are associated colloids different from these colloids.
(I) The colloidal particles in multi-molecular colloids are an assemblage of atoms or tiny molecules having a diameter of less than 1 nm. The molecules in the aggregate are held together by Van der...
Define lyophilic and lyophobic sols. Give one example of each type. Why are hydrophobic sols easily coagulated?
Lyophilic sols - Lyophilic sols are colloidal sols made by combining ingredients like gum, gelatin, starch, and others in a liquid called the dispersion medium. These sols are reversible in nature....
How do pressure and temperature affect the adsorption of gases on solids?
Effect of pressure : Because adsorption is a reversible process that is accompanied by a decrease in pressure, adsorption increases as pressure rises. Effect of temperature : According to...
Write the classification of colloidal solutions on the basis of physical states of the dispersed phase and dispersion medium.
Colloidal solutions can be classified as follows on the basis of their dispersed phase and dispersion medium : Dispersed phase Dispersion medium Type of colloid Example 1. Solid Solid Solid Sol...
Why is adsorption an exothermic process?
The process of adsorption is always exothermic. There are two ways to understand this which are as follows :- (I) The residual forces on the adsorbent's surface are reduced as a result of...
What is the role of adsorption in heterogeneous catalysis?
Heterogeneous catalysis is a catalytic process in which the catalyst and reactants are present in different phases. This form of heterogeneous catalytic action is explained by the adsorption theory....
What is the activation of adsorbent? How is it achieved?
Activation of adsorbent is the process of increasing the adsorption power of the adsorbent. The following methods are used to activate adsorbents: (I) Increasing the adsorbent surface area. This can...
What is an adsorption isotherm? Describe Freundlich’s adsorption isotherm.
The plot of the amount of adsorption (x/m) against the pressure of the gas (P) at constant temperature is known as the adsorption isotherm (T). Three cases arise from the graph which are as follow...
Write the factors influencing the adsorption of a gas on a solid.
Factors influencing the adsorption of gas on a solid:- (1) Nature of the gas : Easily liquefiable gases, such as NH3, HCl, etc., have strong Van der Waal forces, so they are adsorbed to a greater...
Why is a finely divided substance more effective as an adsorbent?
Because adsorption is a surface phenomenon, it is directly proportional to the surface area. Due to its large surface area, a finely split material acts as a good adsorbent. With an increase in...
Write at least 5 differences between physisorption and chemisorption.
Physisorption Chemisorption The adsorbate attaches to the surface of the adsorbent by weak van der Waal’s forces of attraction. The adsorbate...
Write the difference between absorption and adsorption illustrating using one example of each.
Absorption is the phenomenon of uniform distribution of a substance throughout the bulk of the solid and liquid. It is a bulk phenomenon. For example, absorption of water into the bulk of a sponge....