The correct option is (B) transitive but not symmetric
Given aRb ⇒ a is brother of b.
This does not mean b is also a brother of a as b can be a sister of a.
Therefore, R is not symmetric.
aRb ⇒ a is brother of b.
and bRc ⇒ b is brother of c.
So, a is brother of c.
Thus, R is transitive.