Ans: When a cation of higher valence is added to an ionic solid as an impurity to it, the cation of higher valence replaces more than one cation of lower valence so as to keep the crystal electrically neutral. As a result, some sites become vacant. For example, when is added to , each ion replaces two Nat ions. However, one Sr ion occupies the site of one ion and the other site remain vacant. Hence, vacancies are introduced.
Explain how vacancies are introduced in an ionic solid when a cation of higher valence is added as an impurity in it.
Explain how vacancies are introduced in an ionic solid when a cation of higher valence is added as an impurity in it.