In an experiment on the specific heat of a metal, a 0.20 kg block of the metal at 150 °C is dropped in a copper calorimeter (of water equivalent 0.025 kg) containing 150 cm3 of water at 27 °C. The final temperature is 40 °C. Compute the specific heat of the metal. If heat losses to the surroundings are not negligible, is your answer greater or smaller than the actual value for the specific heat of the metal?
In an experiment on the specific heat of a metal, a 0.20 kg block of the metal at 150 °C is dropped in a copper calorimeter (of water equivalent 0.025 kg) containing 150 cm3 of water at 27 °C. The final temperature is 40 °C. Compute the specific heat of the metal. If heat losses to the surroundings are not negligible, is your answer greater or smaller than the actual value for the specific heat of the metal?

Solution:

Given the information in the question:

Mass of the metal block, m = 0.20 kg = 200 g
The initial temperature of the metal block,  = 1500C
The final temperature of the metal block,  = 400C
Copper calorimeter has water equivalent of mass, m1= 0.025 kg = 25 g
Volume of water, V = 150 cm3
Mass (M) of water at temperature T = 270C is 

Specific heat of water, Cw
Let Specific heat of the metal be c

Evaluating the decrease in the temperature of the metal block  
Thermal expansion (increase in temperature of the water and calorimeter system),

Heat gains or losses cause temperature, condition, or work changes. Heat is energy transfer. An object’s energy changes when it gains or loses it.

Heat lost by the metal = Heat gained by the water + heat gained by the  calorimeter

mCT1 = (M+m1)Cw

C = [(M+m1)Cw]/mT1

= [(150 +25) x 4.186

=(175 x 4.186

= 9523.15/22000

= 0.43 

Thus, answer is 0.43 

Unless some heat is lost to the surrounding environment, the specific heat of metal will be less than its true value.