Two ideal gas thermometers A and B use oxygen and hydrogen respectively. The following observations are made: a) What is the absolute temperature of the normal melting point of sulphur as read by thermometers A and B? (b) What do you think is the reason behind the slight difference in answers of thermometers A and B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?
Two ideal gas thermometers A and B use oxygen and hydrogen respectively. The following observations are made: a) What is the absolute temperature of the normal melting point of sulphur as read by thermometers A and B? (b) What do you think is the reason behind the slight difference in answers of thermometers A and B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?

Solution:

(a) Given:

Triple point of water, T= 273.16K.

Pressure in thermometer A at the  triple point, PA =1.25×105 Pa

Normal melting point of sulphur = T1

Pressure in thermometer A at this temperature, P1=1.797×105 Pa

According to Charles law, the following relationship exists:

PA/T=P1/T1

T1 = P1 T/PA

= (1.797×105×273.16)/1.25×105

=392.69 K

This means that while using thermometer A, we can determine the absolute temperature of sulfur’s typical melting point: 392.69 K.

(b) The pressure in thermometer B at the triple point of water, PB =0.2×10Pa

The temperature in thermometer B at the normal melting point (T1) of sulfur is, P1 =  0.287×105 Pa

According to Charles law, we can write the relation:
PB/T=P1/T1
T1 = P1 T/PB​​

T= (0.287×10× 273.16)/0.2×105
=391.98 K

As a result, the absolute temperature of sulfur’s usual melting point, as measured by thermometer B, was determined as 391.98 K.

(b)

The reason for the mismatch is that, in practice, the gases do not behave in the same way as ideal gases. 
If the reading is taken at very low pressure such that the gases behave perfectly, it is possible to lessen the discrepancy.