Solution:
(a) Given:
Triple point of water, T= 273.16K.
Pressure in thermometer A at the triple point, PA =1.25×105 Pa
Normal melting point of sulphur = T1
Pressure in thermometer A at this temperature, P1=1.797×105 Pa
According to Charles law, the following relationship exists:
PA/T=P1/T1
T1 = P1 T/PA
= (1.797×105×273.16)/1.25×105
=392.69 K
This means that while using thermometer A, we can determine the absolute temperature of sulfur’s typical melting point: 392.69 K.
(b) The pressure in thermometer B at the triple point of water, PB =0.2×105 Pa
The temperature in thermometer B at the normal melting point (T1) of sulfur is, P1 = 0.287×105 Pa
According to Charles law, we can write the relation:
PB/T=P1/T1
T1 = P1 T/PB
T1 = (0.287×105 × 273.16)/0.2×105
=391.98 K
As a result, the absolute temperature of sulfur’s usual melting point, as measured by thermometer B, was determined as 391.98 K.
(b)