A mercury lamp is a convenient source for studying the frequency dependence of photoelectric emission since it gives a number of spectral lines ranging from the UV to the red end of the visible spectrum. In our experiment with rubidium photo-cell, the following lines from a mercury source were used:
\lambda_{1}=3650 \AA \lambda_{2}=4047 \AA \lambda_{3}=4358 \AA \lambda_{4}=5461 \AA, \lambda_{5}=6907 \AA. The stopping voltages, respectively, were measured to be: \mathbf{V}_{01}=1.28 \mathrm{~V}, \mathrm{~V}_{02}=0.95 \mathrm{~V}, \mathrm{~V}_{03}=0.74 \mathrm{~V}, \mathrm{V}_{04}=0.16 \mathrm{~V}, \mathrm{~V}_{05}=0 \mathrm{~V}.Determine the value of Planck’s constant \mathrm{h}, the threshold frequency and work function for the material.
A mercury lamp is a convenient source for studying the frequency dependence of photoelectric emission since it gives a number of spectral lines ranging from the UV to the red end of the visible spectrum. In our experiment with rubidium photo-cell, the following lines from a mercury source were used:
\lambda_{1}=3650 \AA \lambda_{2}=4047 \AA \lambda_{3}=4358 \AA \lambda_{4}=5461 \AA, \lambda_{5}=6907 \AA. The stopping voltages, respectively, were measured to be: \mathbf{V}_{01}=1.28 \mathrm{~V}, \mathrm{~V}_{02}=0.95 \mathrm{~V}, \mathrm{~V}_{03}=0.74 \mathrm{~V}, \mathrm{V}_{04}=0.16 \mathrm{~V}, \mathrm{~V}_{05}=0 \mathrm{~V}.Determine the value of Planck’s constant \mathrm{h}, the threshold frequency and work function for the material.

The following relation can be derived from photoelectric effect,
eV_{o}=hv-\phi_{o}

Work function of the metal, \Phi_{0}=\mathrm{hv}-\mathrm{eV}_{0}

\Phi_{0}=(h c / \lambda)-e V_{0}

V_{0}=\frac{h}{e} \nu-\frac{\phi_{0}}{e}---(1)

Here,

\mathrm{V}_{0} is the Stopping potential
\mathrm{h} is the Planck’s constant
\mathrm{e} is the Charge on an electron
\mathrm{v} is the Frequency of radiation

\Phi_{0} is the Work function of a material

As we know, stopping proportional is directly proportional to the frequency from the relation,

Frequency, v= Speed of light (c) / Wavelength (\lambda)

Using this above equation, we can calculate the frequency of various lines

v_{1}=c/\lambda_{1}=3 \times 10^{8} / 3650 \times 10^{-10}

=8.219 \times 10^{14} \mathrm{~Hz}

v_{1}=c/\lambda_{2}=3 \times 10^{8} / 4047 \times 10^{-10}

=7.412 \times 10^{14} \mathrm{~Hz}

v_{1}=c/\lambda_{3}=3 \times 10^{8} / 4358 \times 10^{-10}

=6.88 \times 10^{14} \mathrm{~Hz}

v_{1}=c/\lambda_{4}=3 \times 10^{8} / 5461 \times 10^{-10}

=5.493 \times 10^{14} \mathrm{~Hz}

v_{1}=c/\lambda_{5}=3 \times 10^{8} / 6907 \times 10^{-10}

=4.343 \times 10^{14} \mathrm{~Hz}

The above values can be plotted in a graph

A straight line can be seen in the graph. At 5 \times 10^{14} \mathrm{~Hz}, it crosses the y-axis. This is the frequency at which the threshold is reached. The frequency less than the threshold frequency is represented by point D.

Slope of the straight line will be =A B / C B=(1.28-0.16) /(8.214-5.493) \times 10^{14}

Using equation (1), the slope can be written as

h / e=(1.28-0.16) /(8.214-5.493) \times 10^{14}

h=\left(1.12 \times 1.6 \times 10^{-19}\right) /\left(2.726 \times 10^{14}\right)

=6.573 \times 10^{-34} \mathrm{~J} \mathrm{~s}

The work function of the metal is expressed as,

\Phi_{0}=\mathrm{hv}_{0}

=\left(6.573 \times 10^{-34} \times 5 \times 10^{14}\right)

=3.286 \times 10^{-19} \mathrm{~J}

=3.286 \times 10^{-19} / 1.6 \times 10^{-19}

\Phi_{0}=2.054 \mathrm{eV}