A silver article generally turns black when kept in the open for a few days. The article when rubbed with toothpaste again starts shining. (a) Why do silver articles turn black when kept in the open for a few days? Name the phenomenon involved. (b) Name the black substance formed and give its chemical formula.
A silver article generally turns black when kept in the open for a few days. The article when rubbed with toothpaste again starts shining. (a) Why do silver articles turn black when kept in the open for a few days? Name the phenomenon involved. (b) Name the black substance formed and give its chemical formula.

Solution:

A reaction between silver and H2S in the atmosphere results in the formation of Silver Sulphide, which is a dark brown compound with a sulfuric acid smell. Corrosion is the term used to describe this phenomenon.
Silver Sulphide is the dark-colored compound that results from the reaction.

2Ag+ H2S →Ag2S+H2