(a) Using the Bohr’s model, calculate the speed of the electron in a hydrogen atom in the n = 1, 2, and 3 levels. (b) Calculate the orbital period in each of these levels.
(a) Using the Bohr’s model, calculate the speed of the electron in a hydrogen atom in the n = 1, 2, and 3 levels. (b) Calculate the orbital period in each of these levels.

Answer –

  • Let the orbital speed of the electron in the ground state level of an hydrogen atom, n1= 1, be given by v. For charge (e) of an electron, vis given by the relation –

    \[{{v}_{1}}=\frac{{{e}^{2}}}{{{n}_{1}}4\pi {{\in }_{0}}\left( \frac{h}{2\pi } \right)}=\frac{{{e}^{2}}}{2{{\in }_{0}}h}\]

Where,

the electronic charge is given by, e = 1.6 × 10−19 C

 

    \[{{\in }_{0}}\]

 is the permittivity of free space equal to 8.85 × 10−12 N−1 C 2 m−2

h is the Planck’s constant, given =  6.62 × 10−34 J s

Therefore the orbital speed becomes,

    \[{{v}_{1}}=\frac{{{\left( 1.6\text{ }\times \text{ }{{10}^{-19}} \right)}^{2}}}{2\times ~8.85\text{ }\times \text{ }{{10}^{-12}}\times 6.62\text{ }\times \text{ }{{10}^{-34}}}=0.0218\times {{10}^{8}}\]

    \[{{v}_{1}}=2.18\text{ }\times \text{ }{{10}^{6}}m/s\]

Similarly, we can write the relation for the corresponding orbital speed for level  n2= 2, given by –

    \[{{v}_{2}}=\frac{{{e}^{2}}}{{{n}_{2}}2{{\in }_{0}}h}\]

    \[{{v}_{2}}=\frac{{{\left( 1.6\text{ }\times \text{ }{{10}^{-19}} \right)}^{2}}}{2\times 2\times ~8.85\text{ }\times \text{ }{{10}^{-12}}\times 6.62\text{ }\times \text{ }{{10}^{-34}}}\]

    \[{{v}_{2}}=1.09\times {{10}^{6}}m/s\]

Similary the orbital velocity for level n3= 3 is given by –

    \[{{v}_{3}}=\frac{{{e}^{2}}}{{{n}_{3}}2{{\in }_{0}}h}\]

    \[{{v}_{3}}=\frac{{{\left( 1.6\text{ }\times \text{ }{{10}^{-19}} \right)}^{2}}}{3\times 2\times ~8.85\text{ }\times \text{ }{{10}^{-12}}\times 6.62\text{ }\times \text{ }{{10}^{-34}}}\]

Therefore, the speed of the electron for n=1, n=2, and n=3 is 2.18×106m/s, 1.09×106m/s and 7.27 × 10m/s in a hydrogen atom.

b)

Suppose, Trepresents the orbital period of the electron when it is in the energy level n1= 1.

We know that the Orbital period is related to orbital speed as:

    \[{{T}_{1}}=\frac{2\pi {{r}_{1}}}{{{v}_{1}}}\]

Where r1 represents the radius of the orbit given by

    \[{{r}_{1}}=\frac{{{n}_{1}}^{2}{{h}^{2}}{{\in }_{0}}}{\pi m{{e}^{2}}}\]

Where,

h is the Planck’s constant = 6.62 × 10−34 J s

e is the Charge on an electron = 1.6 × 10−19 C

ε0 is the Permittivity of free space = 8.85 × 10−12 N−1 C2 m−2

m is the Mass of an electron = 9.1 × 10−31 kg

So, orbital period is given by –

    \[{{T}_{1}}=\frac{2\pi }{{{v}_{1}}}\times \frac{{{n}_{1}}^{2}{{h}^{2}}{{\in }_{0}}}{\pi m{{e}^{2}}}\]

    \[{{T}_{1}}=\frac{2\pi \times {{\left( 1 \right)}^{2}}\times {{\left( 6.62\text{ }\times \text{ }{{10}^{-34}} \right)}^{2}}\times 8.85\text{ }\times \text{ }{{10}^{-12}}}{2.18\times {{10}^{6}}\times \pi \times 9.1\times {{10}^{-31}}\times {{\left( 1.6\text{ }\times \text{ }{{10}^{-19}}~ \right)}^{2}}}\]

    \[{{T}_{1}}=1.527\text{ }\times \text{ }{{10}^{-16}}s\]

Similarly for level n= 2, we can write time period as –

    \[{{T}_{2}}=\frac{2\pi {{r}_{2}}}{{{v}_{2}}}\]

Where r2 represents the radius of the orbit given by

    \[{{r}_{2}}=\frac{{{n}_{2}}^{2}{{h}^{2}}{{\in }_{0}}}{\pi m{{e}^{2}}}\]

So, we get –

    \[{{T}_{2}}=\frac{2\pi \times {{\left( 2 \right)}^{2}}\times {{\left( 6.62\text{ }\times \text{ }{{10}^{-34}} \right)}^{2}}\times 8.85\text{ }\times \text{ }{{10}^{-12}}}{1.09\times {{10}^{6}}\times \pi \times 9.1\times {{10}^{-31}}\times {{\left( 1.6\text{ }\times \text{ }{{10}^{-19}}~ \right)}^{2}}}=1.22\times {{10}^{-15}}s\]

Again, similarly proceeding we get the time period for level n= 3 –

    \[{{T}_{2}}=\frac{2\pi \times {{\left( 3 \right)}^{2}}\times {{\left( 6.62\text{ }\times \text{ }{{10}^{-34}} \right)}^{2}}\times 8.85\text{ }\times \text{ }{{10}^{-12}}}{7.27\times {{10}^{5}}\times \pi \times 9.1\times {{10}^{-31}}\times {{\left( 1.6\text{ }\times \text{ }{{10}^{-19}}~ \right)}^{2}}}=4.12\times {{10}^{-15}}s\]

Therefore, 1.52×10-16s, 1.22×10-15s and 4.12 × 10-15s are the orbital periods in given levels.