Describe the manufacture of H2SO4 by contact process.
Describe the manufacture of H2SO4 by contact process.

The steps which are required in the production of Sulphuric Acid by the contact process are mentioned as follows:

Step 1:

Sulphide ores or Sulphur are burnt in air to form sulphur dioxide or SO2​.

Step 2:

By a reaction with oxygen, SO2​ is converted into sulphur trioxide or SO3​ in the presence of vanadium pentoxide or V2O5​ as a catalyst.

2S{{O}_{2}}(g)+{{O}_{2}}(g)\xrightarrow{{{V}_{2}}{{O}_{5}}}2S{{O}_{3}}(g)

Step 3:

SO3​​ produced is absorbed on H2​SO4​ to give H2​S2​O7​ (oleum).

The reaction can be written as follows:

    \[S{{O}_{3}}+{{H}_{2}}S{{O}_{4}}\to {{H}_{2}}{{S}_{2}}{{O}_{7}}\]

The oleum obtained is then diluted to obtain H2​SO4 ​of the desired concentration.

Generally, in practice, the plant is operated at 2 bar pressure and 720 K temperature. The sulphuric acid which is thus obtained has a purity around 96-98%.