Estimate the average mass density of a sodium atom assuming its size to be about 2.5 Å. (Use the known values of Avogadro’s number and the atomic mass of sodium). Compare it with the mass density of sodium in its crystalline phase: 970 kg m–3. Are the two densities of the same order of magnitude? If so, why?
Estimate the average mass density of a sodium atom assuming its size to be about 2.5 Å. (Use the known values of Avogadro’s number and the atomic mass of sodium). Compare it with the mass density of sodium in its crystalline phase: 970 kg m–3. Are the two densities of the same order of magnitude? If so, why?

Answer

According to the question the diameter of sodium is 2.5 Angstrom

= 2.5 x 10-10 m

Therefore, the radius will be half of the above value, i.e., 1.25 x 10-10 m

Expression for the volume of sodium atom is

V= (4/3)πr3

Putting values and solving

= (4/3) x (22/7) x (1.25 x 10-103

V = 8.177 x 10-30 m3

Mass of 1 mole atom of sodium = 23 g

M = 23 x 10-3 kg

We know that the 1 mole of sodium contains 6.023 x 1023 atoms

Therefore, the mass of one sodium atom will be given by –

M= 23 x 10-3/6.023 x 1023

M = 3.818 x 10-26 kg

We know that the expression for atomic mass density of sodium is

ρ = M/V =3.818 x 10-26/8.177 x 10-30

ρ = 0.46692 x 104= 4669.2 kg m-3

Therefore, 4669.2  kg m-3 is the density of sodium in its solid state but in the crystalline phase its density is 970 kg m-3.

As a result, they are in a different order. Atoms are tightly packed in the solid state, but in the crystalline state, they organize themselves in a void-filled sequence. As a result, the density of the solid phase is larger than that of the crystalline phase.