Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?

In the given table, we can find the oxidation numbers of the elements in the first half of the first row of transition elements with increasing atomic number:

Here, we can find that except Sc all other metals have a +2 oxidation state. With an increase in atomic number from 21 to 25, i.e., from Sc to Mn, there is an increase in number of electrons from 1 to 5.

Sc (+2) = d1

Ti (+2) = d2

V (+2) = d3

Cr (+2) = d4

Mn (+2) = d5 When these metals lose two electrons from their 4s orbital, they attain +2 oxidation state. Since the number of d electrons in (+2) oxidation state also increases from Ti(+2) to Mn(+ 2), the stability of +2 state increases (as d-orbital is attaining more and more closer to half-filled stability). Mn (+2) has d5 electrons (that is half-filled d orbital, which is highly stable).