For M2+/M and M3+/M2+ systems the EV values for some metals are as follows:
Cr2+/Cr = -0.9V       Cr3/Cr2+ = -0.4 V
Mn2+/Mn = -1.2V    Mn3+/Mn2+ = +1.5 V Fe2+/Fe = -0.4V Fe3+/Fe2+ = +0.8 V Use this data to comment upon: (i) the stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+ and (ii) the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
For M2+/M and M3+/M2+ systems the EV values for some metals are as follows:
Cr2+/Cr = -0.9V       Cr3/Cr2+ = -0.4 V
Mn2+/Mn = -1.2V    Mn3+/Mn2+ = +1.5 V Fe2+/Fe = -0.4V Fe3+/Fe2+ = +0.8 V Use this data to comment upon: (i) the stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+ and (ii) the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

(i) The reduction potentials for the given pairs increase in the given order:

Mn2+ / Mn < Cr2+ / Cr < Fe2+ /Fe

So, the oxidation of Fe to Fe2+ is not as easy as the oxidation of Cr to Cr2+ and the oxidation of Mn to Mn2+. Thus, these metals can be arranged in the increasing order of their ability to get oxidised as: Fe < Cr < Mn.

(ii) The Eθ value for Fe3+/Fe2+ has a higher value than that for Cr3+/Cr2+ and lower value than that for Mn3+/Mn2+. So, the reduction of Fe3+ to Fe2+ is easier than the reduction of Mn3+ to Mn2+, but not as easy as the reduction of Cr3+ to Cr2+. Hence, Fe3+ is more stable than Mn3+, but less stable than Cr3+. These metal ions can be arranged in the increasing order of their stability as: Mn3+ < Fe3+ < Cr3+.