Option A 6p-orbital and 7 unpaired electrons
Option B 6p-orbital and 6 unpaired electrons
Option C 7p-orbital and 6 unpaired electrons
Option D 7p-orbital and 7 unpaired electrons
Solution: Correct Option B
The free radical of Benzyl is aromatic. It follows Huckel’s rule, which states that it contains 6π electrons in the p-orbital of carbon atoms and that these electrons are delocalized in the p-orbital.
![\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{-2}](https://www.learnatnoon.com/s/wp-content/ql-cache/quicklatex.com-c5a91864ba7e1e0ed1b5d273d822f5e5_l3.png "Rendered by QuickLaTeX.com")
(b) ![\left[\mathrm{Pd}(\mathrm{CN})_{4}\right]^{2-}](https://www.learnatnoon.com/s/wp-content/ql-cache/quicklatex.com-ffda616d3dbe7dc8925722e87005924e_l3.png "Rendered by QuickLaTeX.com")
(c) ![\left[\mathrm{PdCl}_{4}\right]^{2-}](https://www.learnatnoon.com/s/wp-content/ql-cache/quicklatex.com-90cc6a4f4d42dee46e06d6f8ed516b7a_l3.png "Rendered by QuickLaTeX.com")
(d) ![\left[\mathrm{NiCl}_{4}\right]^{2}](https://www.learnatnoon.com/s/wp-content/ql-cache/quicklatex.com-149ee5c95bd9cfcc4405704fba2e1bab_l3.png "Rendered by QuickLaTeX.com")
(d) all of these