Cu2S and FeS are present in copper matte. When a hot blast of air passes through a molten matte in a silica coated converter, the matte’s FeS oxidises to FeO. FeSiO3 (slag) is formed when FeO interacts with SiO2 (silica) .
2FeS + 3O2 ⇒ 2FeO + 2SO2
FeO + SiO2 ⇒ FeSiO3
Cu2S is oxidised to Cu2O , which then reacts with Cu2S to produce copper metal when all of the iron has been removed as slag.
2Cu2S + 3O2 ⇒ 2CuO2 + 2SO2
2Cu2O + Cu2S ⇒ 6Cu + SO2