When working with low-grade copper ores, bacteria or acids are utilised to leach the copper in the presence of air. Copper is introduced to the solution as Cu2+ ions in this method:
Cu + 2H+ + ½ O2 ⇒ Cu2+ + 2H2O
The solution so obtained is then treated with H2 or scrap iron to get copper metal.
Cu + 2H+ ⇒ 2H2+ + Cu