How much energy is required to ionise a H atom if the electron occupies n = 5 orbit? Compare your answer with the ionization enthalpy of H atom (energy required to remove the electron from n =1 orbit).
How much energy is required to ionise a H atom if the electron occupies n = 5 orbit? Compare your answer with the ionization enthalpy of H atom (energy required to remove the electron from n =1 orbit).

The expression for the ionization energy is given by,

E_{n} =\frac{-(2.18\times 10^{-18})Z^{2}}{n^{2}}

Where Z denotes the atomic number and n is the principal quantum number

For the ionization from n_{t}=5 to n_{2} =\infty,

\Delta E=E_{\infty }-E_{5 }=[(\frac{-(2.18\times 10^{-18}\, J)(1)^{2}}{(\infty )^{2}})-(\frac{-(2.18\times 10^{-18}\, J)(1)^{2}}{(5 )^{2}})]=0.0872\times 10^{-18}\, J

\Delta E=8.72\times 10^{-20}\, J

Therefore, the required energy for the ionization of hydrogen from n = 5 to n = ∞ = Energy required for n1 = 1 to n = ∞, is 8.72\times 10^{-20}\, m \Delta E=E_{\infty }-E_{5 }

=[(\frac{-(2.18\times 10^{-18}\, J)(1)^{2}}{(\infty )^{2}})-(\frac{-(2.18\times 10^{-18}\, J)(1)^{2}}{(1 )^{2}})]

=2.18\times 10^{-18}\, J

\Delta E=2.18\times 10^{-18}\, J