Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl ( primary, secondary, tertiary ), vinyl, or aryl halides.
Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl ( primary, secondary, tertiary ), vinyl, or aryl halides.

(i) m-ClCH2C6H4CH2C(CH3)3

(ii) o-Br-C6H4CH(CH3)CH2CH3

Solution:

(i) 1 – Chloromethyl – 3 − ( 2, 2 – dimethylpropyl ) benzene

(Primary benzyl halide)

(ii) 1 − Bromo − 2 – ( 1 − methylpropyl ) benzene

(Aryl halide)