Despite the fact that warmth is a way work yet warms consumed by the framework under certain particular conditions is free of way. What are those conditions? Clarify.
Despite the fact that warmth is a way work yet warms consumed by the framework under certain particular conditions is free of way. What are those conditions? Clarify.

solution:

 

Warmth is free of the way under 2 conditions:

 

  1. At the point when the volume of the framework is kept steady

 

By first law of thermodynamics:

 

    \[\begin{array}{*{35}{l}} q\text{ }=\text{ }\Delta U\text{ }+\text{ }\left( -\text{ }w \right)  \\ ~  \\ what's\text{ }more,\text{ }-\text{ }w\text{ }=\text{ }p\Delta V  \\ ~  \\ Along\text{ }these\text{ }lines\text{ },\text{ }q\text{ }=\text{ }\Delta U\text{ }+\text{ }p\Delta V  \\ ~  \\ \Delta V\text{ }=\text{ }0\text{ }\left( at\text{ }steady\text{ }volume \right)  \\ ~  \\ Thus,\text{ }qv\text{ }=\text{ }\Delta U\text{ }+\text{ }0\text{ }=\text{ }\Delta U=\text{ }change\text{ }in\text{ }inner\text{ }energy  \\ \end{array}\]

  1. At the point when the strain of the framework is kept consistent –

 

    \[\begin{array}{*{35}{l}} At\text{ }consistent\text{ }tension,\text{ }qp=\text{ }\Delta U\text{ }+\text{ }p\Delta V  \\ ~  \\ However,\text{ },\text{ }\Delta U\text{ }+\text{ }p\Delta V\text{ }=\text{ }H  \\ ~  \\ In\text{ }this\text{ }manner\text{ },\text{ }qp\text{ }=\text{ }H\text{ }=\text{ }change\text{ }in\text{ }enthalpy.  \\ \end{array}\]