What are the oxidation number of the underlined elements and how do you rationalise your results?\mathrm{CH}_{3} \mathrm{COOH}
What are the oxidation number of the underlined elements and how do you rationalise your results?\mathrm{CH}_{3} \mathrm{COOH}

Solution:

\underline{\mathrm{C}} \mathrm{H}_{3} \underline{\mathrm{C}} \mathrm{OOH}

 

C2x+14O2
\mathrm{C}_{2}^{\mathrm{x}}+1_{4} \mathrm{O}_{2}

Let x be the oxidation no. of C.

Oxidation no. of 0=-2

Oxidation no. of \mathrm{H}=+1

Then,

2(x)+4(+1)+2(-2)=0

2 x+4-4=0

x=0

Therefore, average oxidation no. of C is 0 . Both the carbon atoms are present in different environments so they

cannot have same oxidation no. Therefore, carbon has oxidation no. of +2 and _2 in \mathrm{CH}_{3} \mathrm{COOH}.