Why E° esteems for Mn, Ni and Zn are more negative than anticipated?
Why E° esteems for Mn, Ni and Zn are more negative than anticipated?

Solution:

Mn2+(3d5) and Zn2+(3d10) have half-filled and filled d orbitals which give them dependability and accordingly like to remain as such and not get diminished. With respect to Ni2+(3d8), it has exceptionally high regrettable hydration enthalpy which gets adjusted by first and second ionization enthalpy.