solution: \[\begin{array}{*{35}{l}} W=\text{ }\text{ }2.303nRT\text{ }log\text{ }\left( p1/p2 \right)  \\ ~  \\ =\text{ }\text{ }2.303\text{ }\times \text{ }1\text{ }mol\text{ }\times \text{...

solution: From the given enthalpy outline it tends to be said the adjustment of enthalpy ∆H is positive for the response, for example it will be endothermic. In any case, when goes to the suddenness...

solution: Among these two cycles, simultaneously or response (b) the expected energy/enthalpy change is contributing component to the immediacy.

solution: At the point when an optimal gas in a pressure, where the adjustment of tension is completed in boundless advances for example through a reversible interaction, the work done can be...

solution:   From this chart we can get the be the work done on the ideal gas encased in the chamber in 1 stage: the region covered by P-V diagram (concealed locale) is the real worth of the...

  solution:   In the accompanying cyclic ( 1 → 2 →3 →1 ) measure the underlying and last point is something very similar (for example 1). Subsequently the enthalpy change or\[H=\text{ }0\]...

Arrangement:   Alternative (ii) is the appropriate response. w (reversible) < w (irreversible) Region under the bend is more noteworthy in irreversible pressure than that of reversible...

solution:   \[\begin{array}{*{35}{l}} Measure\text{ }of\text{ }work\text{ }done\text{ }=\text{ }-\text{ }pext\text{ }V  \\ ~  \\ =\text{ }\text{ }2\text{ }bar\text{ }\times \text{ }\left(...

solution:   For the given response : \[2H2\left( g \right)\text{ }+\text{ }O2\left( g \right)\text{ }\to 2H2O\left( l \right)\] the standard enthalpy of response is \[Hr\Theta \text{ }=\text{...

solution:   The enthalpy of vapourisation is given \[\begin{array}{*{35}{l}} for\text{ }1\text{ }mole\text{ }of\text{ }CCl4\text{ }=\text{ }30.5\text{ }kJ\text{ }mol1  \\ ~  \\...

solution:   For the response   \[H2\left( g \right)\text{ }+\text{ }Br2\left( g \right)\text{ }\to 2HBr\left( g \right)\] \[\begin{array}{*{35}{l}} Enthalpy\text{ }change  \\ ~  \\ =\text{...

solution:   The warmth of ignition ∆Hc of graphite (for example carbon) is given as \[=\text{ }20.7\text{ }kJ\] for 1g of graphite (C).   \[1\text{ }mole\text{ }of\text{ }Carbon\text{...

solution:   For an optimal gas, the distinction between these two \[is\text{ }CP\text{ }\text{ }CV\text{ }=\text{ }nR,\] the all inclusive gas consistent and \[where\text{ }n=\text{ }no.\text{...

solution:   \[\begin{array}{*{35}{l}} For\text{ }water,\text{ }molar\text{ }warmth\text{ }limit\text{ }=\text{ }18\text{ }x\text{ }Specific\text{ }warmth\text{ }or  \\ ~  \\ Cp~=\text{...

solution:   Work done in vacuum is determined by :   \[\begin{array}{*{35}{l}} -\text{ }w\text{ }=\text{ }Text\text{ }\left( Vinitial\text{ }\text{ }Vfinal\text{ } \right)  \\ ~  \\...

solution:   Warmth is free of the way under 2 conditions:   At the point when the volume of the framework is kept steady   By first law of thermodynamics:  ...

solution:   Gibbs energy for a response in which all reactants and items are in standard state. ΔrG° is identified with the harmony consistent of the response as follows  ...

solution:   Water has solid hydrogen bonds and the high extremity likewise accumulates in coming about it to bubble at higher temperatures. Thus water has a higher molar enthalpy than CH3)2CO....

solution:   State capacities: enthalpy, entropy, temperature and free energy.   Way works: Heat and work

solution:   The standard molar entropy of H20 (1) is 70 J K-1 mol-1. The strong type of H20 is ice. In ice, atoms of H20 are less irregular than in fluid water. In this way, molar entropy of...

solution:   As warm balance submits to the zeroth law of thermodynamics, temperature of framework and environmental factors will be a similar when they are in warm balance.

solution:   The numerical connection which relates these three boundaries is \[\Delta S\text{ }=\text{ }qrev/T\]   where ΔS is the adjustment of entropy and T represents...

solution:   Sublimation of the metal(ΔsubHΘ) →Ionization of the metal (ΔiHΘ) →Dissociation of the non-metal (ΔdissHΘ) →Gain of electrons by the non-metal(ΔegHΘ)   \[\Delta f\text{ }H\theta...

solution:   For 1 C-H bond, the bond energy will be equivalent to 1/4 that of the enthalpy of atomisation   \[=\text{ }\left( 1665/4 \right)\text{ }=\text{ }416.25\text{ }kJ\text{...

solution:   For the response, A→B the development of B goes through a few middle of the road responses with various enthalpy esteems Δr H1, ΔrH2, ΔrH3… .., and the general enthalpy change is Δr...

solution:   Enthalpy change of a response is determined as   : Σbond enthalpy of reactants-Σbond enthalpy of items   for the deterioration \[\begin{array}{*{35}{l}} 2NH3\left( g...

solution:   The given response \[CaO\left( s \right)\text{ }+\text{ }CO2\left( g \right)\text{ }\to CaCO3\left( s \right)\] is demonstrating that it is happening in the standard type of 1 mole...

  solution:   Among the two fluids, water has a higher enthalpy of vapourisation (burning-through higher warmth energy).   Thusly, ∆Hvapourisation (water) > ∆Hvapourisation...

solution:   Enthalpy change of vapourisation for \[1\text{ }mole\text{ }=\text{ }40.79\text{ }kJ\text{ }mol1\] enthalpy change of vapourisation for \[2\text{ }moles\text{ }of\text{ }water\text{...

solution:   Choice (I) and (iii) are the appropriate responses

solution:   Alternative (iii) and (iv) are the appropriate responses. work done at 600 K is double the work done at 300 K. Since each case includes isothermal extension of an optimal gas, there...

solution:   Alternative (iii) and (iv) are the appropriate responses. Gas grows or diffuses in accessible space suddenly, e.g., spillage of cooking gas gives smell of ethyl mercaptan...

solution:   Choice (I) and (ii) are the appropriate responses. For an exothermic response\[,\text{ }qp~=\text{ }-\text{ }ve,\text{ }\gamma H\text{ }=\text{ }-\text{ }ve\]

solution:   Alternative (I) and (iv) are the appropriate responses. Thermodynamics manages interrelation of different types of energy and their change into one another. It additionally manages...

solution:   Alternative (ii) is the appropriate response.   ∆G gives a basis for suddenness at consistent strain and temperature.   (I) If ∆G is negative (< 0). the cycle is...

solution:   Choice (I) is the appropriate response. Enthalpy of sublimation of a substance is equivalent to enthalpy of combination + enthalpy of vapourisation.   Sublimation is immediate...

solution:   Choice (iii) is the appropriate response. Warmth of arrangement of a compound might be positive or negative.

solution:   Choice (iii) is the appropriate response.   x > y because same bonds are formed  in reactions (i) and (ii)  but bonds between reactant molecules are broken only in reaction...

solution:   Choice (iii) is the appropriate response. \[\begin{array}{*{35}{l}} \left( a \right)\text{ }C\text{ }\left( graphite \right)\text{ }+\text{ }O2\text{ }\left( g \right)\text{ }\to...

solution:   Alternative (iii) is the appropriate response. During the method involved with freezing energy is released,which is consumed by the environmental factors. Therefore,the entropy off...

solution:   Choice (iii) is the appropriate response. With the expectation of complimentary extension w = 0 For adiabatic cycle q = 0 From first law of thermodynamics,  ...

solution:   Choice (ii) is the appropriate response.

solution:   Choice (iii) is the appropriate response. Exothermic reaction for combustion of one mole of butane is represented as \[\left( iii \right)\text{ }C4H10\left( g \right)\text{...

solution:   Alternative (iii) is the appropriate response. The particular warmth of a substance is the warmth needed to raise the temperature of 1 gram of a substance by one degree (1 K or 1...